????????(II) ????????

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????????(II) ????????
????????? ???????
??.?.???. ????? [7789-43-7]
??? ???? 24610
???.??.?.??.???. ????? GF9595000
SMILES [Co](Br)Br
  • InChI=1/2BrH.Co/h2*1H;/q;;+2/p-2

????????
CoBr 2 , CoBr 2 .6H 2 O, CoBr 2 .2H 2 O
?????? ?????????? 218.7412 g/mol (anhydrous)
326.74 g/mol (hexahydrate)
??????? Bright green crystals (anhydrous)
Red-purple crystals (hexahydrate)
??????? 4.909 g/cm 3 (anhydrous)
2.46 g/cm 3 (hexahydrate)
???????? ?????? 678 °C (1,252 °F; 951 K)
anhydrous:
66.7 g/100 mL (59 °C)
68.1 g/100 mL (97 °C)
hexahydrate:
113.2 g/100 mL (20 °C)
????????? 77.1 g/100 mL (ethanol, 20 °C)
58.6 g/100 mL (methanol, 30 °C)
soluble in methyl acetate , ether , alcohol , acetone
????????
?????? ????????
Rhombohedral , hP3 , SpaceGroup = P-3m1, No. 164
???????????? ????????
octahedral
?????????
R-???????? R36, R37, R38
S-???????? S26, S37, S39, S45, S28A
????? ?????? {{{value}}}
Lethal dose or concentration ( LD , LC ):
LD 50 ( median dose )
406 mg/kg (oral, rat)
??????? ??????????
??? ??????? {{{value}}}
??? ?????????
iron(II) bromide
nickel(II) bromide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
checkY   verify  ( what is   checkY ☒N  ?)
Infobox references

???????? (II) ???????? (CoBr 2 ) ?? ?????? ????????. ??? ?? ????? ?? ?????? ???????, ?????? ??????????. ????????? ?????? ???????????? ?? ???????????? ?????????????.

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??? ????(????????), ???????? (II) ???????? ??????? ????????? ???????? ????????????. ?????????????? 100 °C ???? ?????????? ????????? ?????????????? ???????? ?????? ?????????? ???????????:

CoBr 2 .6H 2 O → CoBr 2 .2H 2 O + 4 H 2 O

?????? 130 °C ?? ??????? ???? ????? ??? ????(????????) ???? ??????????:

CoBr 2 .2H 2 O → CoBr 2 + 2 H 2 O

??? ????(????????) ???? 678 °C ???? ??????????. [1] [2]

???? ????????? ? ????, ???????? (II) ???????? ???????? ???? ???????? ??? ???????? (II, III) ???????, ???????? ???????? ??????? ??????????,

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???????? (II) ???????? ?????????????? ??????? ???????? ???????????? ???? ?????? ?? ?????????? ????? ????????:

Co(OH) 2 (s) + 2HBr(aq) → CoBr 2 .6H 2 O(aq)

??? ???? ???????? (II) ????????, ????? ????????, ???? ???????? ????? ????????? ????????? ?????? ????? ????????. [3] [4] [5]

??????????? , ????????

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????????? ?????? ???????? ???? ??????????????????????? (III) ?????????? ???????? (II) ???????? ????? ?? ??????? , ??? ?????????? ????? ???????? ?????? ?????????????. [6]

2 CoBr 2 + 8 NH 3 + 2 NH 4 Br + H 2 O 2 → 2 [Co(NH 3 ) 5 Br]Br 2 + 2 H 2 O

???????? (II) ???????? ??? ?????? ?????????? ???????? ????????? ???????? ????????? ?? ??????????? ???? ????????????????.

.

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???????? (II) ????? ???????? ???????? ????? ???????? ???? ??????? ????????????. [7] ???????? ?? ???? ???????? ???? ????.

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  1. Cobalt Bromide Supplier & Tech Info Archived 2015-04-04 at the Wayback Machine American Elements
  2. WebElements Periodic Table of the Elements
  3. WebElements Periodic Table of the Elements | Cobalt | Essential information
  4. "Chemical Properties and Reaction Tendencies" . Archived from the original on 2008-02-19 . Retrieved 2014-12-27 .
  5. "Pilgaard Solutions: Cobalt" . Archived from the original on 2009-01-22 . Retrieved 2014-12-27 .
  6. Diehl, Harvey; Clark, Helen; Willard, H. H.; Bailar, John C. (1939). "Bromopentamminocobalti Bromide". Inorganic Syntheses . Inorganic Syntheses. 1 : 186. doi : 10.1002/9780470132326.ch66 . ISBN   9780470132326 .
  7. "??????? ????" (PDF) . Archived from the original (PDF) on 2007-06-25 . Retrieved 2014-12-26 .