??????? ??????????????? ?????????????????? ???????.
???????? ??????
(
isocyanic acid
) ?????? HNCO ????
??????????? ??????????
????? ???
?????? ???????????
. ??? 1830 ??????? ??????? ??????? ????????? ????? ????????? ???????????????.
[2]
??????? ?????????? ????????
?????????
????????? ???????????????? ??????? ?????. 23.5
????
?????????
????????????? ???
?????????
?????????.
????????
???????
???? ???????????
???????
,
??????
,
????????
???????
????????
???? ?????? ??????? ?????????????? ??????????? ??????? ???? ???????????????????? ??????????? ???????? ?????? ?????.
????????? ??????? ???????
[
????
]
??????????? ????????
????? ???????????????
????????
????????? ???? ???????????
?????? ????????
??????
????????? ??????????
?????????? ??????????????? ?????? ???????? ?????????? ????????????.
[3]
- H
+
+ NCO
-
→ HNCO
???? ?????????????? ????????? ????????
???????? ????????
????????????????? ?????????????? ???????? ?????????? ????????????.
- C
3
H
3
N
3
O
3
→ 3 HNCO
???????? ??????
?????????????
???????? ????????
???????????????
???????
??????????
?????????.
- HNCO + H
2
O → CO
2
+ NH
3
??????? ???????? ????? ???????? ?????? ????????????? ???????? ???????? ???????? ?????? ???????
?????????
???? ???????????????? ????????. ????????????? ???????? ???? ?????? ???? ???? ???? ???? ???????????? ????????????????????.
????
??????? ????????????? ???????????
??????????????
[4]
????? ??????????? ???????
??????????????
???????????? ???????? ?????? ?????????? ?????????? ?????????????.
???
????????I???????????
???????????? ???????????? ?????????
??????????
????????.
- HNCO + RNH
2
→ RNHC(O)NH
2
.
??????? ?????????????? ???? ??????? ?????????????????.
?????????????
???????????
?????? ??????????
???????? ?????? ???????????? ????????? ??????????
???????????????
????????.
???????? ?????? ?????????, ??????? ???? ????? ???????? ??????
????
??????????? ???????????????. ???????? ????? ????? ?????????
[5]
??? ????????????????????. ?????????? ?????? ?????? ??????? ????????? ??????????? ????????? ???????? ?????? ????????????.
??????????: ?????? ???????? ????????? ????????
[
????
]
???????? ?????? ????????? ???????????????? ????????????? ??????????? ???? ?????? ?????? ??????
?????? ????????
????????? ???????????. ??? ???????? ?????????? ???????? ?????????????????.
[6]
????????? ?????? ?????????? ????????????? ??????? ?????????? ???????????? ???????? ?????? ???????????? ???????????? ????????????.
[4]
?????????????????? ????????? ???????????????? ????????????????? ???????? ?????????? ?????? ???????????????? ??????? ??????.
?????? ???????? ???????? ???????? ??????????????????? ????????
????????? ?????????????
?????????????
?????
[7]
.
???????????
[
????
]
- ↑
Pradyot Patnaik.
Handbook of Inorganic Chemicals
. McGraw-Hill, 2002,
ISBN 0-07-049439-8
- ↑
Liebig, J.; Wohler, F. (1830).
"Untersuchungen uber die Cyansauren"
.
Ann. Phys.
20
(11): 394.
doi
:
10.1002/andp.18300961102
. Bibcode:
1830AnP....96..369L
.
http://gallica.bnf.fr/ark:/12148/bpt6k15105c/f377.table
.
- ↑
Fischer, G.; Geith, J.; Klapotke, T. M.; Krumm B. (2002).
"Synthesis, Properties and Dimerization Study of Isocyanic Acid"
.
Z. Naturforschung
57b
(1): 19?25
.
http://www.znaturforsch.com/ab/v57b/s57b0019.pdf
.
- ↑
4.0
4.1
A. S. Narula, K. Ramachandran “Isocyanic Acid” in Encyclopedia of Reagents for Organic Synthesis, 2001, John Wiley & Sons, New York.
????
:
10.1002/047084289X.ri072m
Article Online Posting Date: April 15, 2001.
- ↑
Preidt, Robert.
"Chemical in Smoke May Pose Health Risk"
.
MyOptumHealth
. AccuWeather
. ????????????? ????
14 September
2011
.
- ↑
Jacox, M.E.; Milligan, D.E. (1964). "Low-Temperature Infrared Study of Intermediates in the Photolysis of HNCO and DNCO".
Journal of Chemical Physics
40
(9): 2457?2460.
doi
:
10.1063/1.1725546
. Bibcode:
1964JChPh..40.2457J
.
- ↑
Kurzer, Frederick (2000).
"Fulminic Acid in the History of Organic Chemistry"
.
Journal of Chemical Education
77
(7): 851?857.
doi
:
10.1021/ed077p851
. Bibcode:
2000JChEd..77..851K
.
https://archive.org/details/sim_journal-of-chemical-education_2000-07_77_7/page/851
.
?????????? ?????
[
????
]
?????????
[
????
]
- Handbook of Chemistry and Physics
, 65th. Edition, CRC Press (1984)
???? ??????????
[
????
]
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