??????? ??????????????? ?????????????????? ???????.
?????????
[1]
Full structural formula of acetone with dimensions
|
Skeletal formula of acetone
|
|
Ball-and-stick model of acetone
|
Space-filling model of acetone
|
|
????????
|
???????
????????
?????
|
???? ????????
?????????? ????????
[2]
β-?????? ????????
[2]
???????????
[3]
2-?????????
[2]
?????????? ??????????????
[4]
|
?????????????
|
|
67-64-1
Y
|
3DMet
|
B00058
|
Abbreviations
|
DMK
|
Beilstein Reference
|
635680
|
ChEBI
|
CHEBI:15347
Y
|
ChEMBL
|
ChEMBL14253
Y
|
ChemSpider
|
175
Y
|
EC number
|
200-662-2
|
Gmelin Reference
|
1466
|
InChI=1S/C3H6O/c1-3(2)4/h1-2H3
Y
Key: CSCPPACGZOOCGX-UHFFFAOYSA-N
Y
InChI=1/C3H6O/c1-3(2)4/h1-2H3
Key: CSCPPACGZOOCGX-UHFFFAOYAF
|
????? -3D ?????????
|
Image
|
KEGG
|
D02311
Y
|
?.??.?
|
Acetone
|
???????
|
180
|
??.?.??.? ???
|
AL3150000
|
|
UNII
|
1364PS73AF
Y
|
UN number
|
1090
|
????????
|
|
C
3
H
6
O
|
???????????? ???
|
58.08 g·mol
?1
|
???????
|
???????? ??????
|
????
|
?????????, ??????????????, ??????????? ?????????? ??????
|
????????
|
0.791 ?? ??,??
?3
[6]
|
??????????? ???
(p
K
a
)
|
24.2
|
?????????? ???
(p
K
b
)
|
-10.2
|
????????? ????????
(
n
D
)
|
1.35900
|
??????????
|
0.3075 cP
|
??????????
|
????????? ??????
|
????????? ?????????? (Dipole moment)
|
2.91 D
|
??????????????
|
Std enthalpy of
formation
Δ
f
H
o
298
|
-250.03-(-248.77) ???? ????
?1
|
Std enthalpy of
combustion
Δ
c
H
o
298
|
-1.772 ???????? ????
?1
|
???? ??????
???????????
S
o
298
|
200.4 ?? ??
?1
????
?1
|
??????? ??????
,
C
|
125.45 ?? ??
?1
????
?1
|
?????????
|
GHS pictograms
|
|
GHS signal word
|
??????
|
|
H225
,
H319
,
H336
|
|
P210
,
P261
,
P305+351+338
|
??? ?????????
|
F
Xi
|
R-????????????
|
R11
,
R36
,
R66
,
R67
|
S-????????????
|
(S2)
,
S9
,
S16
,
S26
|
??????????? ?????????
|
?17 °??
|
Threshold Limit Value
|
500 ????????????? ???????? (TWA), 750 ????????????? ???????? (STEL)
|
Lethal dose or concentration (
LD
,
LC
):
|
|
>2000 ??.??/??.??, ??????? (???)
|
?????????? ??????????
|
?????????? ??????????
|
?????????
????????????
|
???????? ????? ??????????? ??????? ????????????? ??????? ??????
????????? ???????? ??????? ????? ?????? ???????? (25°C, 100kPa) ?????????.
|
|
|
?????????
(Acetone)
?????? C
3
H
6
O ?????? (CH3)2CO ????
??????????? ??????????
????? ???
???? ?????????
???????????
. ??????????? ???? ????????? ??? ??????????????. ??? ??????????????, ??????? ???????? ?????????? ?????????????. ????????? ?????????? ????? ??? ???????????? ??????.
???????????
????????? ??????? ???? ???????? ????????? ?????.
????????? ?????????? ?????????. ???? ??? ?????????????? ?????????????. ??????????? ?????????? ??????????????, ???? ????? ????????? ??? ??????? ?????????, ??????? ???????????? ????????? ??????????? ????????????????????. 2010 ??? ??????? ??????? ????? ????????? 6.7 ????????? ?????? ????????? ???????? ?????????????. ??? ??????????????, ???????? ??????????????? ??????? ?????????? ? ???????????? ??????? ????? ??????????? ??????????????????
[7]
[8]
. ???? ??????????? ??????? ??????????? ????????? ????????? ????????????. ?????? ??????????? ?????????, ????????? ?????????????, ??? ????????????????? ????????????. ????? ???????????????? ???????????? ????????? ????????????????????.
?????? ???????? ????? ???????????? ????????? ???? ?????? ???????? ??????????????? ??????? ?????????????????. ??? ??????? ????? ??????? ?????????? ??????. ???????? ?????? ??????????????????? ????? ?????? ??? ???????? ????????????. ??? ??????????? ????????????? ?????????????? ???????????????? ?????????????? ???????????? ??????????? ???????????? ????? ????????? ??????????????. ??????????? ?????????, β- ???????? ??????????? ??????, ??????? ????????? ?????? ????? ??????????? ??????????? ???????? ??????????? ??????? ?????????????? ????????? ??????? ??????????? ?????? ??????????????. ????????????? ??????? ??????? ???????? ??????? ???????????????? ????????? ??????????? ??? ??????????.
??????
[
????
]
????????? ????? ??????? ???????????? ???? ?????? ????????? ???????? ?????????????. ?? ??????????? ????? ???? ?????????????? ??????? ???? ???????? ???????? ?????? ????????? ??????????????
[9]
.
1832 ??? ????? ???????? ???????????? ???? ???????????? ?????? ??????? ????????? ???????????? ???????? ???? ?????? ??????? ???????????????? ????? ???????????? ????? ????????
[10]
[11]
. 1833 ??? ????? ??????? ???????? ????????? ??????? ????????? ???? ?????? ????????? ???? ???????????. ?????????? ?????????? ??????? ?????? ???? ????????? ??? ???? ?????????? ?????????? ????????. ??????? ????????? ?????? ???? ?????????? ?????????? ?????? ??????? ????????? ???? ??? ???? ?????????? ???????? ????????? ????? ???????????
[12]
. 1852 ??? ??????????? ????????? ??????? ???????????? ????????? ????????????? ????????? ?????? ???????? ????????? ?????? ????????????????? ;
[13]
. ?????? ??????? ???????? ???????? ??????? ?????????? ??????? ????????? ?????????? ??? ??????? ????????
[14]
. ????????? ?????????? ?????? ???????? ?????????????? ?????????? ???????????? ????????????
[15]
[16]
. 1861 ??? ?????????????? ?????????? ?????? ????? ?????????? ????????????
[17]
. ??????? ????????? ???????????? ???? ?????????? ???? ??????????? ????????????. ??????? ????? ???? ????????? ?????? ?????????? ????????? ??????????? ???? ????? ????????? ????????????????
[18]
.
???????? ????????
[
????
]
????? ???? ????????? ?????? ???? ???????? ??????????? ??????????????? ????? ???????? ????? ???????? ???????????????. ??????? ??????????? ??????? ???? ?????????? ??????? ????????????????? ???? ???? ????????? ????????? ????? ?????? ?????????? ?????????? ???????? ??????????. ???? ??????????? ???? ???????? ????????? ??????????. ?????????????, ???????? ???? ????? ???? ??????????? ??????????????? ???????????????. ?????????????????? ?????????? ??????? ?????? ????????? ???????? ?????????. ??????????? ?????? ????? ?????????????.
????????? ??????????????????? ????
[
????
]
????????? ???????? ????????????? ?????????? ?? ??? ?????????????? ???????????????? ??????? ?????? ????????? ??????????? ??????????????
[19]
. ????????????????? ?????? ??????????? ????????????. 30 ???????????? ???????? ???????????????? ???????????? ????????????????? ?????? ????????? ???????? ??????????? ?????????????. ?????? ????????? ??????? ????????? ????????? ????????? ???????????? ????????? ????????? ?????? ???????? ??????? ?????????????.
???????????
[
????
]
- ↑
Merck Index
, 11th Edition,
58
- ↑
2.0
2.1
2.2
"Acetone"
.
NIST Chemistry WebBook
. USA: National Institute of Standards and Technology.
- ↑
Klamt, Andreas (2005).
COSMO-RS: From Quantum Chemistry to Fluid Phase Thermodynamics and Drug Design
. Elsevier. pp. 92?94.
??????????? ?????????? ???
0444519947, 9780444519948
.
- ↑
Ash, Michael; Ash, Irene (2004).
Handbook of preservatives
. Synapse Information Resources, Inc. p. 369.
??????????? ?????????? ???
1890595667
.
- ↑
"Acetone ? PubChem Public Chemical Database"
.
The PubChem Project
. USA: National Center for Biotechnology Information.
- ↑
"Acetone CHROMASOLV® Plus, for HPLC, ≥99.9%"
. Sigma-Aldrich
. ????????????? ????
15 September
2011
.
- ↑
Acetone
, World Petrochemicals report, January 2010
- ↑
Stylianos Sifniades, Alan B. Levy, "Acetone" in Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH, Weinheim, 2005.
- ↑
Gorman, Mel; Doering, Charles (1959). "History of the structure of acetone".
Chymia
5
: 202?208.
- ↑
Dumas, J. (1832)
"Sur l'esprit pyro-acetique"
(On pyro-acetic spirit),
Annales de Chimie et de Physique
, 2nd series,
49
: 208?210.
- ↑
Liebig, Justus (1832)
"Sur les combinaisons produites par l'action du gas olefiant et l'esprit acetique"
(On compounds produced by the action of ethylene and acetic spirit),
Annales de Chimie et de Physique
, 2nd series,
49
: 146?204 (
especially 193?204
).
- ↑
Bussy, Antoine (1833)
"De quelques Produits nouveaux obtenus par l’action des Alcalis sur les Corps gras a une haute temperature"
(On some new products obtained by the action of alkalies on fatty substances at a high temperature),
Annales de Chimie et de Physique
, 2nd series,
53
: 398?412 ; see
footnote on pp. 408?409
.
- ↑
Williamson, A. W. (1852)
"On Etherification,"
Journal of the Chemical Society
,
4
: 229?239 ; (
especially pp. 237?239
).
- ↑
Gerhardt, Charles (1853)
"Researches sur les acids organiques anhydres"
(Research on anhydrous organic acids),
Annales de Chimie et de Physique
, 3rd series,
37
: 285?342 ;
see p. 339.
- ↑
Kekule, Auguste (1865)
"Sur la constitution des substances aromatiques,"
Bulletin de la Societe chimique de Paris
,
1
: 98?110 ; (
especially p. 110
).
- ↑
Kekule, Auguste (1866)
"Untersuchungen uber aromatischen Verbindungen"
(Investigations into aromatic compounds),
Annalen der Chemie und Pharmacie
,
137
: 129?196 ; (
especially pp. 143?144
).
- ↑
Loschmidt, J. (1861)
Chemische Studien
Vienna, Austria-Hungary: Carl Gerold's Sohn.
- ↑
Chaim Weizmann
. chemistryexplained.com
- ↑
Vujasinovic, M; Kocar, M; Kramer, K; Bunc, M; Brvar, M (2007). "Poisoning with 1-propanol and 2-propanol".
Human & Experimental Toxicology
26
(12): 975.
doi
:
10.1177/0960327107087794
.
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| |
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| |
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| |
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| |
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| |
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????? (?) ?????? ???????? ????????
| |
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|
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| |
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| |
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| |
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