???????????, ??? ????????? ???????????.
Boron,
00
B
![](//upload.wikimedia.org/wikipedia/commons/thumb/1/19/Boron_R105.jpg/220px-Boron_R105.jpg) boron (β-rhombohedral)
[1]
|
|
Pronunciation
|
(
BOHR
-on
)
|
---|
????????????
| α-, β-rhombohedral, β-tetragonal (and
more
)
|
---|
Appearance
| black-brown
|
---|
|
|
????????
| group 13 (boron group)
|
---|
??????
| period 2
|
---|
????????
|
p-block
|
---|
????????? ????????
| [
He
] 2s
2
2p
1
|
---|
Electrons per shell
| 2, 3
|
---|
|
Phase
at
STP
| solid
|
---|
??????????
| 2349
K
(2076 °C, 3769 °F)
|
---|
??????????
| 4200 K (3927 °C, 7101 °F)
|
---|
Density
when liquid (at
m.p.
)
| 2.08 g/cm
3
|
---|
????????? ???????
| 50.2
kJ/mol
|
---|
Heat of vaporization
| 508 kJ/mol
|
---|
Molar heat capacity
| 11.087 J/(mol·K)
|
---|
Vapor pressure
P
(Pa)
|
1
|
10
|
100
|
1 k
|
10 k
|
100 k
|
at
T
(K)
|
2348
|
2562
|
2822
|
3141
|
3545
|
4072
|
|
|
Oxidation states
| ?5, ?1, +1, +2,
+3
[2]
[3]
(a mildly
acidic
oxide)
|
---|
Electronegativity
| Pauling scale: 2.04
|
---|
???????? ????
| - 1st: 800.6 kJ/mol
- 2nd: 2427.1 kJ/mol
- 3rd: 3659.7 kJ/mol
- (
more
)
|
---|
???????? ???
| empirical: 90
pm
|
---|
????????? ???????
| 84±3 pm
|
---|
Van der Waals radius
| 192 pm
|
---|
Spectral lines
of boron
|
|
Natural occurrence
| primordial
|
---|
?????????? ???
|
rhombohedral
|
---|
Speed of sound
thin rod
| 16,200 m/s (at 20 °C)
|
---|
Thermal expansion
| β form: 5?7 μm/(m?K) (at 25 °C)
[4]
|
---|
????????
| 27.4 W/(m?K)
|
---|
Electrical resistivity
| ~10
6
Ω?m (at 20 °C)
|
---|
????????
| diamagnetic
[5]
|
---|
????????????
| ?6.7·10
?6
cm
3
/mol
[5]
|
---|
Mohs hardness
| ~9.5
|
---|
??.?.??? ?????
| 7440-42-8
|
---|
|
Discovery
| Joseph Louis Gay-Lussac
and
Louis Jacques Thenard
[6]
(30 June 1808)
|
---|
First isolation
| Humphry Davy
[7]
(9 July 1808)
|
---|
|
Template:infobox boron isotopes does not exist
|
??????: Boron
|
references
|
References
These references will appear in the article, but this list appears only on this page.
- ↑
Van Setten
et al. 2007, pp. 2460?1
- ↑
Zhang, K.Q.; Guo, B.; Braun, V.; Dulick, M.; Bernath, P.F. (1995).
"Infrared Emission Spectroscopy of BF and AIF"
(PDF)
.
J. Molecular Spectroscopy
.
170
: 82.
Bibcode
:
1995JMoSp.170...82Z
.
doi
:
10.1006/jmsp.1995.1058
.
- ↑
Melanie Schroeder.
"Eigenschaften von borreichen Boriden und Scandium-Aluminium-Oxid-Carbiden"
(PDF)
(in ??????). p. 139.
- ↑
Holcombe Jr., C. E.; Smith, D. D.; Lorc, J. D.; Duerlesen, W. K.; Carpenter; D. A. (October 1973). "Physical-Chemical Properties of beta-Rhombohedral Boron".
High Temp. Sci
.
5
(5): 349?57.
- ↑
5.0
5.1
Haynes, William M., ed. (2016).
CRC Handbook of Chemistry and Physics
(97th ed.).
CRC Press
. p. 4.127.
ISBN
9781498754293
.
- ↑
Gay Lussac, J.L.; Thenard, L.J. (1808).
"Sur la decomposition et la recomposition de l'acide boracique"
.
Annales de chimie
.
68
: 169?174.
- ↑
Davy H (1809).
"An account of some new analytical researches on the nature of certain bodies, particularly the alkalies, phosphorus, sulphur, carbonaceous matter, and the acids hitherto undecomposed: with some general observations on chemical theory"
.
Philosophical Transactions of the Royal Society of London
.
99
: 39?104.
doi
:
10.1098/rstl.1809.0005
.
- ↑
8.0
8.1
"Atomic Weights and Isotopic Compositions for All Elements"
. National Institute of Standards and Technology
. Retrieved
2008-09-21
.
- ↑
Szegedi, S.; Varadi, M.; Buczko, Cs. M.; Varnagy, M.; Sztaricskai, T. (1990). "Determination of boron in glass by neutron transmission method".
Journal of Radioanalytical and Nuclear Chemistry Letters
.
146
(3): 177.
doi
:
10.1007/BF02165219
.
Five of these are
named references
. They may be cited in the containing article as
- <ref name="v1" /> for the source
Infrared Emission Spectroscopy of BF and AIF
- <ref name="magnet" /> for the source from
Handbook of Chemistry and Physics
- <ref name="NISTic" /> for the source
Atomic Weights and Isotopic Compositions for All Elements
- <ref name="Lussac" /> for the source by Gay-Lussac
- <ref name="Davy" /> for the source by Davy
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