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Temperature programmed surface reaction test of Co?Ni bimetallic aerogel catalysts for methane reforming

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Abstract

CH 4 temperature programmed surface reaction (TPSR) and CH 4 oxy-CO 2 TPSR are applied to test Ni (10Ni), Co (10Co) and Co?Ni (5Co5Ni) aerogel catalysts in the CH 4 oxy-CO 2 reforming reaction. Monometallic 10Ni outperforms 10Co and bimetallic 5Co5Ni aerogel catalysts in the CH 4 -TPSR test. The CH 4 activation temperature (AT) of 10Ni and 5Co5Ni is 160?°C lower than that of 10Co, indicating that CH 4 can be activated more effectively on 10Ni and 5Co5Ni. As a result, the critical temperature (CT) of 10Ni and 5Co5Ni in the CH 4 oxy-CO 2 TPSR test are 680?°C and 695?°C, whereas 10Co shows no CT in the test. The CH 4 oxy-CO 2 TPSR test also reveals that although CTs of the catalyst are independent of the reduction pretreatment, the catalytic oxidation abilities for carbon species are greatly promoted after reduction. The calcined samples activate CH 4 via the combination of combustion and partial oxidation, while the reduced sample activate CH 4 mainly via combustion. Furthermore, the reduced 5Co5Ni activates and completes CH 4 oxidation at temperatures 60?°C and 128?°C lower than those of 10Ni, suggesting its higher ability to catalyze the oxidation of carbon species generated in CH 4 reforming, which could be account for its better performance than those of the monometallic catalysts.

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Acknowledgements

The financial supports from National Science Foundation of China (No. 21306231), China Scholarship Council (No. 201706375005), China Postdoctoral Science Foundation (No. 2018M632988) and Natural Science Foundation of Hunan province (No. 2018JJ3662) are gratefully acknowledged.

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Authors and Affiliations

  1. School of Metallurgy and Environment, Central South University, Changsha, 410083, China

    Lin Chen,?Qingyu Huang,?Duchao Zhang,?Weifeng Liu?&?Tianzu Yang

  2. Post-Doctoral Joint Research Center, Hunan Jinwang Bismuth Industry Co., Ltd., Chenzhou, 423000, China

    Lin Chen

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  1. Lin Chen
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  2. Qingyu Huang
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  3. Duchao Zhang
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  4. Weifeng Liu
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  5. Tianzu Yang
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Correspondence to Duchao Zhang .

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Chen, L., Huang, Q., Zhang, D. et al. Temperature programmed surface reaction test of Co?Ni bimetallic aerogel catalysts for methane reforming. Reac Kinet Mech Cat 126 , 951?962 (2019). https://doi.org/10.1007/s11144-018-01531-3

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