Carbide chloride

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Carbide chlorides are mixed anion compounds containing chloride anions and anions consisting entirely of carbon . In these compounds there is no bond between chlorine and carbon. But there is a bond between a metal and carbon. Many of these compounds are cluster compounds , in which metal atoms encase a carbon core, with chlorine atoms surrounding the cluster. The chlorine may be shared between clusters to form polymers or layers. Most carbide chloride compounds contain rare earth elements. Some are known from group 4 elements. The hexatungsten carbon cluster can be oxidised and reduced, and so have different numbers of chlorine atoms included.

The carbide chlorides are a subset of the halide carbides, with related compounds including the carbide bromides , and carbide iodides . Cluster compounds similar to these carbides, may instead replace carbon with boron, hydrogen, nitrogen or phosphorus.

List [ edit ]

formula system space group unit cell volume density comment reference
Ca 3 C 3 Cl 2 orthorhombic Cmcm a=3.876, b=13.524, c=11.653 2.47 red [1]
Sc 2 CCl 2 P 3 m 1 a=3.39977 c=8.858 3.24 black [2]
Sc 5 CCl 8 monoclinic C 12/ m 1 a=17.8 b=3.5259 c=12.052 β=130.11 2.99 [2]
Sc 7 C 2 Cl 10 monoclinic C 12/ m 1 a=18.62 b=11.81 β=99.81 3.04 ruby red; moisture sensitive [3] [2]
Ti 6 CCl 14 orthorhombic Cmce a=12.4592 b=12.2458 c=10.9576 2.93 black [2]
YCCl C 12/ m 1 a=6.82 b=3.713 c=9.327 β=94.75 3.85 [2]
Y 2 C 0.7 Cl 2 P 3 m 1 a=3.7022 c=9.195 3.91 silvery grey [2]
Zr 6 CCl 14 orthorhombic Cmce a=14.091 b=12.595 c=11.506 3.43 brown red [4] [2]
KZr 6 CCl 15 orthorhombic Pnma a=18.489 b=13.909 c=9.690 Z=4 2492 dark red; Zr 6 C clusters [5]
Rb 4 Zr 6 CCl 18 C 2/ m a=10.460 b=17.239 c=9.721 β=115.05 Z=2 [6]
Rb[(Zr 6 C)Cl 15 ] orthorhombic Pnma a=18.484,b= 18.962,c=9.708 Z= 4 2505.4 3.12 dark red-brown [7]
Cs 4 [Sc 6 C]Cl 13 tetragonal I 4 1 / amd a = 15.405, c = 10.179 Z=4 green black [8]
Cs[(Zr 6 C)Cl 15 ] orthorhombic Pnma a = 18.513 b = 13.916 c = 9.6383 Z=4 2483.1 dark red [9]
La 2 CCl R 3 m a=3.878 c=16.91 5.74 coppery red [10]
La 2 C 2 Cl monoclinic C 12/ c 1 a=14.77 b=4.187 c=6.802 β=101.5 5.44 gold [11] [10]
La 3 C 3 Cl 2 monoclinic C 12/ c 1 a=7.771 b=12.962 c=6.91 β=104.3 5.16 gold [10]
La 4 C 2 Cl 5 orthorhombic Immm a=3.92 b=7.945 c=19.297 4.67 black [10]
La 4 C 5 Cl 2 monoclinic C 12/ m 1 a=22.57 b=3.91 c=1.019 β=95.69 5.07 gold [10]
La 5 C 2 Cl 9 triclinic P 1 a=8.645 b=8.706 c=11.925 α=84.97° β=85.78° γ=61.31° 4.40 red [10]
La 6 (C 2 ) 3 Cl 4 monoclinic P 2 1 / c a = 7.770, b = 12.962, c = 6.910 and β = 104.30° Z=2 674.4 5.158 gold; sheets of octahedra [12]
La 8 C 8 Cl 5 monoclinic P 12 1 / c 1 a=7.756 b=16.951 c=6.878 β=104.2 5.24 gold [11] [10]
La 8 (C 2 ) 5 Cl 4 monoclinic C 2/ m a = 22.570, b = 3.9300, c = 10.190 β = 95.69° Z=2 899.4 5.071 gold [12]
La 11 C 11 Cl 7 monoclinic P 12 1 / c 1 a=7.77 b=47.038 c=6.901 β=104.28 5.19 gold [10]
La 14 C 14 Cl 9 monoclinic P 1 C 1 a=7.775 b=2.9963 c=6.895 β=104.21 5.19 gold [11] [10]
La 20 C 20 Cl 13 monoclinic P 12 1 / c 1 a=7.762 b=42.941 c=6.903 β=104.26 5.18 black [11] [10]
La 36 C 36 Cl 23 monoclinic P 12 1 / c 1 a=7.764 b=77.055 c=6.897 β=104.26 5.18 grey [11] [10]
K[La 5 (C 2 )]Cl 10 monoclinic P 2 1 / c a=8.5632, b=15.074, 17.115 β=119.74 Z=4 1918.3 3.85 light red [13]
Ce 2 C 2 Cl monoclinic C 12/ c 1 a=14.573, b=4.129, c=6.696, β=101.37 5.71 gold [1]
Ce 2 (C 2 ) 2 Cl monoclinic C 2/ c a = 14.573, b = 4.129, c = 6.696, β = 101.37 ° [14]
Ce 3 CCl 5 monoclinic C 12/ c 1 a=13.899, b=8.71, c=15.765, β=98.22 4.29 orange [1]
Ce 4 CCl 8 monoclinic P 1 C 1 a=13.538, b=10.487, c=22.845, β=126.31 4.35 black [10] [15]
Ce 5 C 2 Cl 9 triclinic P 1 a=8.57, b=8.627, c=11.869, α=84.8, β=85.5, γ=61.29 red [1]
Ce 6 Cl 10 C 2 monoclinic C 12/ c 1 a= 13.899,b= 8.710,c= 15.765,β= 98.22° Z=4 1888.9 [16]
Ce 8 C 8 Cl 5 monoclinic P 12 1 / c 1 a=7.669, b=16.784, c=6.798, β=104.05 5.46 gold [11] [1]
Ce 18 (C 2 ) 9 Cl 11 triclinic P 1 a = 6.771, b = 7.657, c = 18.98, α = 88.90 °, β = 80.32 °, γ = 76.09 ° [14]
Ce 26 (C 2 ) 13 Cl 16 monoclinic P 2 1 / c a = 7.664, b = 54.25, c = 6.796, β = 103.98 ° [14]
K[Ce 5 (C 2 )]Cl 10 monoclinic P 2 1 / c a=8.4739, b=15.017, c=1639 β=119.76 Z=4 1871.2 3.97 red [13]
Pr 3 CCl 5 monoclinic C 12/ c 1 a=13.867 b=8.638 c=15.69 β=97.67 4.37 yellow [2]
Pr 4 C 2 Cl 5 orthorhombic Immm a=3.848 b=7.759 c=17.01 5.00 black [2]
Pr 5 C 2 Cl 9 triclinic P 1 a=8.526 b=8.592 c=11.821 α=84.77 β=85.42 γ=61.26 4.61 brown red [2]
Pr 6 C 2 Cl 10 monoclinic C 2/ c a = 13.687, b = 8.638, c = 15.690, β = 97.67° yellow to green [17]
Pr 8 C 8 Cl 5 monoclinic C 12 1 / c 1 a=7.617 b=16.689 c=6.769 β=103.94 5.57 gold [2]
Pr 11 C 11 Cl 7 monoclinic P 12 1 / c 1 a=7.612 b=6.127 c=6.761 β=103.92 5.56 gold [2]
Pr 14 C 14 Cl 9 monoclinic P 1 c 1 a=7.611 b=29.392 c=6.764 β=103.9 5.56 gold [2]
K{Pr 5 (C 2 )}Cl 10 hexagonal P 6 3 / m a=8.426 c=14.894 Z=2 915.9 dark red [18]
Rb{Pr 5 (C 2 )}Cl 10 hexagonal P 6 3 / m a=8.4499, c=14.976 Z=2 926 4.19 red; trigonal bipyrmamid of Pr containing a C 2 unit [19]
Rb[Nd 5 (C 2 )]Cl 10 hexagonal a=08.398, c=14.88 4.33 dark red [13]
Gd 2 C 2 Cl P 3 m a=3.6902, c=20.308 [10]
Gd 2 C 2 Cl 2 monoclinic P 3 m 1 a=3.7633, c=9.4593 5.69 black; contains C 2 4? [4] [10]
Gd 3 CCl 3 cubic I 4 1 32 a=10.734 6.34 [10]
Gd 4 C 2 Cl 3 orthorhombic Pnma a=10.596, b=3.684, c=19.627 6.58 bronze [10] [20]
Gd 5 C 2 Cl 9 monoclinic P 12 1 / c 1 a=9.182, b=16.12, c=12.886, β=119.86 4.54 black [10]
Gd 5 C 6 Cl 3 monoclinic C 12/ m 1 2.1507,0.37193,1.5331,90,123.34 6.25 bronze [10]
Gd 6 C 3 Cl 5 monoclinic C 12/ m 1 a=16.688,b=3.6969,c=12.824, β=128.26 6.18 grey [10]
Gd 10 C 4 Cl 17 triclinic P 1 a=8.498, b=9.174, c=11.462, α=104.56, β=95.98, γ=111.35 4.70 black; contains C 2 4? [4] [10]
Gd 10 C 4 Cl 18 triclinic P 1 a = 8.498, b = 9.174, c = 11.462, α = 104.56°, β = 95.98°, γ = 111.35°, Z = 1 contains C 2 4? [21] [4]
[Gd 4 (C 2 )](Cl, I) 6 tetragonal P 4/ mbm a = 13.475, c = 12.125, Z = 2 black [22]
Rb 2 [Gd 10 (C 2 ) 2 ]Cl 19 orthorhombic a=1.2228, b=2.2347, c=1.3896 4.31 black [23]
Cs 2 [Gd 10 (C 2 ) 2 ]Cl 19 orthorhombic a=1.2344, b=2.2434, c=1.3924 4.41 black [23]
Cs 3 [Tb 10 (C 2 ) 2 ]Cl 21 monoclinic C 2/ c Z = 4; a = 23.187; b = 12.458; c = 15.02; β = 98.13° black [24]
Lu 2 CCl 2 R 3 m a=3.6017, c=27.16 7.07 brown [10]
Lu 2 CCl 2 P 3 m 1 a= 3.5972, c=9.0925 7.05 [10]
Cs 2 Lu[Lu 6 C]Cl 18 R 3 a = 9.817, c = 27.232, Z = 3 [25]
Hf 6 CCl 14 orthorhombic Cmce a=13.938, b=12.498, c=11.399 5.28 [10]
W 2 CCl 8 orthorhombic Pbca a=11.96 b=12.156 c=10.9576 2.83 black [2]
W 6 CCl 15 monoclinic C 12 1 / c 1 a=9.8831 b=11.8945 c=17.867 β =107.883 5.47 black [2]
W 6 CCl 16 orthorhombic Pnma a=16.637 b=12.958 c=9.797 5.29 black [2]
W 6 CCl 18 P 6 2c a=8.923 c=17.503 4.82 black [2]
W 30 C 2 (Cl,Br) 68 triclinic P 1 a = 12.003, b = 14.862, c = 15.792, α = 88.75°, β = 68.85°, γ = 71.19° Z=1 2472.9 black [26]
Li[W 6 CCl 18 ] hexagonal P 6 3 / m a = 8.8648, c = 17.490 Z=2 1188.2 black [27] [28]
(Bu 4 N)[W 6 CCl 18 ] [29]
(Me 4 N) 2 [W 6 CCl 18 ] [28]
(Bu 4 N) 2 [W 6 CCl 18 ] [29]
(Bu 4 N) 3 [W 6 CCl 18 ] [29]
Na[W 6 CCl 18 ] hexagonal P 6 3 / m a=8.9592 c=17.5226 Z=2 1188.2 [28]
Ca[W 6 CCl 18 ] hexagonal P 6 3 / m a=8.9384 c=17.6526 Z=2 1220.4 [28]
Cu[W 6 CCl 18 ] triclinic P 1 a=8.89 b=8.929 c=17.669 α=81.85 β=80.78 γ=60.39 Z=2 1200.7 5.025 black [30]
Cu(C 2 H 6 OS) 6 [W 6 CCl 18 ] monoclinic C 2/ c a=17.333 b=16.011 c=18.082 β=94.61 Z=4 5001.7 3.035 dark brown [30]
Cu(C 2 H 6 OS) 4 [W 6 CCl 18 ] 2 triclinic P 1 a=9.47 b=12.630 c=13.634 α=104.69° β=90.16° γ=92.99° Z=1 1575.2 4.095 dark violet [30]
Ag[W 6 CCl 18 ] hexagonal P 6 3 / m a=8.874 c=17.58 Z=2 1199 [28]
Cs[W 6 CCl 18 ]·CH 3 OH orthorhombic P 2 1 2 1 2 1 a = 9.6957, b =  14.046, c = 20.238 Z=4 4.623 black; W in trigonal prism around C [27]

References [ edit ]

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  28. ^ a b c d e Weisser, Martina; Burgert, Ralf; Schnockel, Hansgeorg; Meyer, H.-Jurgen (April 2008). "Synthese und Untersuchung von kohlenstoff- und stickstoffzentrierten (Z) trigonal-prismatischen Wolframclustern des Formeltyps A[W6ZCl18]" . Zeitschrift fur anorganische und allgemeine Chemie (in German). 634 (4): 633?640. doi : 10.1002/zaac.200700474 .
  29. ^ a b c Welch, Eric J.; Crawford, Nathan R. M.; Bergman, Robert G.; Long, Jeffrey R. (2003-09-01). "New Routes to Transition Metal-Carbido Species: Synthesis and Characterization of the Carbon-Centered Trigonal Prismatic Clusters [W 6 CCl 18 ] n - ( n = 1, 2, 3)" . Journal of the American Chemical Society . 125 (38): 11464?11465. doi : 10.1021/ja035962v . ISSN   0002-7863 . PMID   13129326 .
  30. ^ a b c Mos, Agnieszka; Strobele, Markus; Meyer, H.-Jurgen (October 2015). "Carbon Centered Trigonal Prismatic Tungsten Clusters [W 6 CCl 18 ] n- ( n = 1, 2) containing Copper(I) and Copper(II): Tungsten Clusters [W 6 CCl 18 ] n- ( n = 1, 2) with Copper(I) and (II)" . Zeitschrift fur anorganische und allgemeine Chemie . 641 (12?13): 2245?2249. doi : 10.1002/zaac.201500571 .
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